Adsorption Mechanism of Chlorpyrifos and Dichlorvos Mixture onto Poly-Sorbent Composite Derived from Waste Plastic Products
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International Journal of Recent Engineering Science (IJRES) |  |
| © 2024 by IJRES Journal | ||
| Volume-11 Issue-2 |
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| Year of Publication : 2024 | ||
| Authors : Sunday O. OLADUNNI, Dauda O. ARAROMI, Wasiat O. BELLO, Victoria, A. ADEYI, Ilesanmi A. OJO, Abass O. ALADE |
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| DOI : 10.14445/23497157/IJRES-V11I2P102 |
How to Cite?
Sunday O. OLADUNNI, Dauda O. ARAROMI, Wasiat O. BELLO, Victoria, A. ADEYI, Ilesanmi A. OJO, Abass O. ALADE, "Adsorption Mechanism of Chlorpyrifos and Dichlorvos Mixture onto Poly-Sorbent Composite Derived from Waste Plastic Products," International Journal of Recent Engineering Science, vol. 11, no. 2, pp. 9-17, 2024. Crossref, https://doi.org/10.14445/23497157/IJRES-V11I2P102
Abstract
Poly-sorbent Composite was derived from discarded Waste Plastic Chairs (WPC), Waste Polyvinyl Chloride pipes (WPVC), Waste Jerry Cans (WJC) and Waste Electronics Casing (WEC), which were collected at a waste plastic collection center. Each waste plastic was washed, milled to 840 μm and acid-acetylated before being mixed to a composite as Activated Waste Plastic Granule Composite (AWPGC). The functional groups on the AWPGC were determined using Fourier Transform Infrared (FT-IR) Spectroscopy. The composite was used for the removal of the Chlorpyrifos (CPF) and Dichlorvos (DDVP) mixture from the aqueous medium, under the effect of varying time and the data obtained was used to evaluate the suitable kinetic models of the process. The FT-IR of AWPGC before adsorption revealed the functional group as hydroxyl, alkanes, carbonyl group, ether and amine group, while after adsorption showed the presence of hydroxyl, aromatic hydrocarbon and silicone. The adsorption kinetic models for both CPF and DDVP fitted most to the pseudo-second-order model, while their best-fitted mass transfer model is Weber Morris.
Keywords
Adsorption, Chlorpyrifos, Dichlorvos, Poly-sorbent, Waste Plastic Products.
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